

I’ve always understood 2 as 2 physically different media - i.e., copies in different folders or partitions of the same disk is not enough to protect against failure of that disk, but a copy on a different disk does. Ideally 2 physically different systems, so failure/fire in the primary system won’t corrupt/damage the backup.
Used to be that HDDs were expensive and using them as backup media would have been economically crazy, so most systems evolved backup media to be slower and cheaper. The main thing is that having /home/user/critical, /home/user/critical-backup, and /home/user/critical-backup2 satisfies 3 copies, but not 2 media.
If you’re already running Pihole, I’d look at other things to do with the Pi.
https://www.adafruit.com/ has a bunch of sensors you can plug into the Pi, python libraries to make them work, and pretty good documentation/examples to get started. If you know a little python, it’s pretty easy to set up a simple web server just to poll those sensors and report their current values. Only slightly more complicated to set up cron jobs to log data to a database and a web page to make graphs.
It’s pretty straightforward to put https://www.home-assistant.io/ in a docker on a Pi. If you have your own local sensors, it will keep track of them, but it can also track data from external sources, like weather & air quality. There a bunch of inexpensive smart plugs ($20-ish) that will let you turn stuff on/off on a schedule or in response to sensor data.
IMO, Pi isn’t great for transport-intensive services like radarr or jellyfin, but, with a Usb HD/SSD might be an option.